This is interesting. I have been having a similar problem with my small biocube, which is mostly acans, zoas and a few chalices on a frag rack. I missed a water change, the alk dropped, I noticed a bunch of pineapple sponges in the back chambers, and then I lost half of my acans. Now I do a water change once a week, and I have been dosing with baking soda and a little magnesium and still my alk seems low. I also have a bloom of what looks like cyano, but it's almost black in color. I wonder if this new algae/bacteria/whatever is using up all the alkalinity? The tank is at least 2 years old, and I've never had this problem before. Luckily, it's only happening in one of my tanks. Did you get any type of algae bloom before this happened?