Here's some good info. You'll have to wait until the PSU study is published to see the results of the testing regarding filter sock/carbon vs skimmer. There were a few posts alluding to the preliminary results that might shock most reefkeepers.
Is a skimmer becoming obsolete
« on: September 18, 2010, 11:18:04 PM »
I have gathered a few points that might be worthy of discussing
What Does a Protein Skimmer Actually Remove from Aquarium Water?
http://www.advancedaquarist.com/2010/2/aafeature
The chemical/elemental composition of skimmate generated by an H&S 200-1260 skimmer on a 175-gallon reef tank over the course of several days or a week had some surprises. Only a minor amount of the skimmate (solid + liquid) could be attributed to organic carbon (TOC); about 29%, and most of that material was not water soluble, i.e., was not dissolved organic carbon. The majority of the recovered skimmate solid, apart from the commons ions of seawater, was CaCO3, MgCO3, and SiO2 - inorganic compounds! The origin of these species is not known with certainity, but a good case can be made that the SiO2 stems from the shells of diatoms. The CaCO3 might be derived from other planktonic microbes bearing calcium carbonate shells, or might come from calcium reactor effluent. To the extent that the solid skimmate consists of microflora, then some proportion of the insoluble organic material removed by skimming would then simply be the organic components (the "guts") of these microflora. These microflora do concentrate P, N, and C nutrients from the water column, and so their removal via skimming does constitute a means of nutrient export
The work of Ken Feldman on protein skimmer efficacy or lack there of is leading us closer to closed systems without sumps. If protein skimmers can only remove 20% of the TOC (total organic carbon), then maybe we should scrap them entirely and spend the (protein skimmer, surface skimmer, sump, plumbing, & return pump) money on better resources. That's a lot of money and energy that can be redirected to more efficient means of TOC reduction. Maybe our protein skimmers should be out in the garage with our bioballs and exercise equipment (as seen on TV)
http://www.reefcentral.com/forums/showpost.php?p=17637377&postcount=4305
To oversimplify, here are some methods...
Biological:
- nitrification (bacteria on substrate surfaces)
- denitrification (bacteria & in-fauna/sand critters in substrate internal structure)
- assimilation (microbes/bacterial film on coral & algae tissue)
- nutrient export (mangroves, algae, and coral harvesting)
Chemical:
- carbon (ROX type is faster)
- granular ferric oxide (GFO phosphate removal)
- aluminum oxide (phosphate removal)
- chemipure (TOC & heavy metal removal)
- polyfilter (TOC & heavy metal removal)
- zeolite (TOC & heavy metal removal)
- protein skimming (TOC & heavy metal removal)
- ozone (oxidation of bacteria, parasites, & TOC/total organic carbon including particulate & dissolved)
- ultraviolet sterilization (oxidation of bacteria, parasites, & TOC/total organic carbon including particulate & dissolved)
- water changes (nutrient export)
Mechanical:
- filter bags/socks
- cartridges
- sponges & pads
- physical removal (settling & siphoning)
Many reef aquarists only employ a few of these methods or do so to a limited extent. Carbon levels are typically elevated in marine aquaria and cause stress to corals and feed nuisance algae. Granular activated carbon (GAC) has proven to be the most effective method of TOC export, removing about 80% at a faster rate than protein skimming. Water changes can remove the remaining excess nutrients and organics as needed.
There is no overwhelming benefit to removing a protein skimmer that is in place, but considering it is the least efficient and most expensive & labour intensive device available, we should think twice about where to put our resources when designing a new tank. The marketing machine has sold us on the newest skimmer trends for years. That manufactured demand focus has now shifted to LED lighting. As John Tullock says "Less technology, more biology".
http://www.reefcentral.com/forums/showpost.php?p=17638248&postcount=4316
Ken Feldman had a nice demonstration in his presentation at MACNA. He showed two pictures of a skimmer cup. One was rich and dark brown with dry foam, while the other one had opaque light brown liquid and wet bubbles. The audience agreed that the darker skimmate was superior. He then disclosed that he used 2.6 oz of coffee grounds and some liquid soap he bubbled with a straw in the "efficient" cup. He placed a dime beside the dried coffee to put it into perspective. The "inefficient" skimmate was created with 10 oz of brown sugar and a little less effort with the straw in the liquid soap. The seemingly less efficient skimmate had five times more "stuff" by dry weight and the dime looked more like a peso next to it.
Unless you have a fancy TOC analyzer, you have no reasonable method of measuring your protein skimmers abilities. There is an easier method where PAR readings can be compared, but even this is out of reach for most hobbyists.
A healthy substrate can oxidize/assimilate detritus as quickly as it forms, providing your flow delivers most of it to the corals and filtration. There is usually a settling point(s) with most systems. It is possible to create a cone that would collect and export detritus automatically. Just make sure fish and inverts don't get exported to
http://www.reefcentral.com/forums/showpost.php?p=17638716&postcount=4323
Re: Is a skimmer becoming obsolete
First of all, I don't want to be known as the guy who told you to "just unplug your skimmer" They do remove 20% of the TOC and do so quickly. I would however advise against spending that extra $500 on the $1200 model.
There have been many successful reef tanks that have not had protein skimmers. There are also quite a few successful tanks that have skimmers that barely skim. The idea of abandoning a protein skimmer is enhanced when you can ditch your open system (sump) at the same time.
The caveat (warning) here is that you need to refocus the protein skimmer resources in other areas of TOC removal and nutrient export. If you follow Ron Shimek's work, you will know that there are many ways of exporting nutrients other than protein skimming. Take a look at the charts here...
http://www.reefkeeping.com/issues/2002-12/rs/feature/index.php
While many hobbyists have refugiums, few exploit them to their fullest potential. A few compact fluorescent lights will grow macro algae, but with a little fine tuning you can harvest enough algae to keep your local health food store stocked
Header tanks (filter tanks above the display) can raise as many problems as sumps. The weight needs to be managed for one, and the water needs to be drained without adding bubbles to the display. One of the obvious advantages is that live food (plankton) can easily migrate from the refuge of the macro algae to the waiting polyps of the display tank.
Activated carbon (GAC) is another filtration method that is often carried out passively. ROX type carbon should be used and replaced frequently. In most cases the water clarity and colour is enough of an indication. Carbon should be placed in the path of moving water but in a way that limits channeling and clogging. A fluidized bed filter helps with this.
Ozone is another underutilized tool. You don't need a protein skimmer to dose ozone. If you increase the production of your refugium then you need to deal with the secondary metabolites (algae toxins) that are a byproduct. Protein skimmers can remove these, but carbon and ozone are more efficient.
Mechanical filters are also more efficient at removing POC (particulate organic carbon) than protein skimmers. Make sure you don't overlook this important filtration device if you omit a skimmer.
There is no significant gas exchange provided by protein skimming that you can't get with good water flow. Take some of the money you are saving and do your flow dynamics right. The air/water interface at the surface is constantly rolling and changing. This is where the chief oxygenation is occurring.
There is a certain peace of mind one gains by having a closed system without an open sump. You should still use a rubbermaid container or liner to catch drips and direct them to a drain. These systems also run silently.
OceanClear makes a modular canister filter system with biological, chemical, UV sterilizer and mechanical options. The only issue I have with them is the lid is quirky and can be difficult to get a good seal. There is a flaw in the mould that leaves a seam where the "O" ring seats on the top. Pentair has a similar line but they are tall and narrow and subsequently difficult to fit under a display tank.
This OceanClear canister has been modified with a 1" compression fitting to hold a heater, a clear acrylic lid for light penetration, a totally inadequate Coralife power compact light (it was 7 years ago), and a bag of carbon. The flow is strong enough to keep the Chaetomorpha algae ball spinning for better light exposure and detritus removal. A second OC canister is attached to this one (located in an adjacent cabinet) with 25 micron mechanical and 18 watt Aqua UV sterilizer. The tank is a 55 gallon reef with only one pump on a 2-Way OceansMotions wave maker.
http://www.reefcentral.com/forums/showpost.php?p=17640641&postcount=4333