You may need to play around with the flow patterns in the tank a little to keep the scum feeding into the overflow. The scum should be skimming off the surface into the overflow.
Also, do you have a lot or a little flow going through the overflow? If it's one of the reef ready oveflow designs with an intake lower in the tank, and the flow is relatively slow, then that lower intake may be taking the bulk of the flow which would then limit the surface skim.