Okay....so here's the deal. Patrick found a store in Amesbury that sells magnesium chloride (around $18/50lb bag). I'd seen it for sale many places, but the bags that I had seen were from a company in the US. That source might be fine, but without an analysis, I am very reluctant to use an icemelt grade of stuff in our tanks. The bags that Patrick found had the SAME source as our group buy, the Dead Sea Works in Israel (I'm not making any political statements here!).
Patrick sent me a sample of the stuff he purchased. It looks very similar in everyway to the stuff we purchased previously in our group buy. The only difference I could see was that the particle size was slightly smaller, put that could be due to lots of different things (how much the stuff was handled, where from the bag the stuff was taken, settling, etc.).
I tested a sample of the 'old' and 'new' lots of magnesium chloride for their ammonium content. In each case I got the same result as I did when I tested a long while back. Both were just at the limit of detection on the equipment I was using. So...worst case: if you were adding this to your tank and bumped up the Magnesium concentration 100 ppm you would be adding LESS than 0.05 ppm ammonium (not enough in a functioning reef tank, IMO, to have any effect, though I probably wouldn't add it to a culture of urchin larva
). I also compared both for pH and they came up about the same at 7.5 pH, this was immediately after prep in RO/DI water. I realize that MgCl2 in DI water has no buffering capacity, so the pH may drift, but I was please to see that the pH was not some crazy number.
Now....the material that is available in Amesbury is certainly not the same lot of material we purchased in the group buy. I am also not certain that it is of the same quality...I just don't know as I have no spec sheet. However, based on the test I performed, and my visual inspection of the stuff, I think that it is PROBABLY safe to use on a tank (DON'T sue me if you tank crashes after you use it please). It may be that the new material (icemelt grade) does not have the same level of quality control. So, if you mix up a batch and plan to use it in your tank, I would keep your eye out for any particulates in the stuff. To be safe you might want to prep the supplement in a clear container, let it sit and then carefully pour it into another container, hopefully leaving any settled particles (rust?, bits of debris?) behind.
Patrick took a photo of the front of the bag and I have posted it here:
The back looks like this, zoomed in on the important part of the back label:
Now, to confuse you all some more...I picked up a bag of Pelletized magnesium chloride from a hardware store in Danvers, also from the Dead Sea Works in Israel. This stuff clearly LOOKS different from the other stuff, but the bag is NEARLY the same (same color and label pattern), just says PELLETIZED on the front. I also for kicks ran this through my ammonium assay and pH. It also came out the same as the others. Still, I'm reluctant to use this simply due to the fact that it Looks different than the stuff we got from the group buy that I KNOW is good (I've used it on my tanks many times with no problems).
I understand that there are several pallets full of the stuff that Patrick sent me at the store in Amesbury. Please do not hoard!
AMESBURY INDUSTRIAL SUPPLY
24 HIGH STREET AMESBURY MA
978.388.1313
To prep your supplement use the following formula:
The formula below creates a magnesium supplement that does not significantly create an imbalance in any other anions in your tank's water. The anions in saltwater are chiefly chloride (Cl-) and sulfate (SO4-2). Bromine is also in there as an anion, but it's slow low that for many years salt manufacturers never even bothered to add it to their mixes, so leaving it out of this supplement is not a big deal at all. The basic formula is:
664 grams MgCl2.6H2O (this is what is at the hardware stores)
113 grams MgSO4.7H2O (Epsom salts, from the drug store costs $1.99 for 3 lbs)
plus enough DI water to make 1 gallon.
Adding this at the rate of about 10 ml/gallon of tank volume (in a stream of water where it will get mixed into the tank quickly) will increase the magnesium level in your tank by about 100 ppm. It's never a good idea to make changes too fast to a tank's water chemistry, so if your tank is low in magnesium by more than 100 ppm I'd still only add 10ml/gallon/day until you are back around 1250-1350 ppm. So, for instance, if your 100 gallon tank were 300 ppm low in magnesium, you'd need about 3 liters, or almost 1 gallon of this solution to get back into the proper range on magnesium.
To dose magnesium correctly you really need to measure it with a decent test kit. I've found the Salivert kit for magnesium to be pretty good and reasonably priced, FWIW.